卤氧化铋BiOX (X = Cl, Br, I)是一种新型的半导体光催材料,与TiO2
相比,其特有的层状结构和可调节的禁带宽度,使其展现出更为优异的光催化性能。在此方面,本文主要介绍了目前卤氧化铋的合成方法、控制手段以及光催化应用中的重要结果,总结了现有提高卤氧化铋光催化特性的主要途径。最后对卤氧化铋材料的光探测研究方向进行了展望。
As a novel semiconductor photocatalytic, BiOX exhibit excellent photocatalytic activities owing to specific layer structure and tunable band gap, compared with TiO
2
. In this review, the recent research and development in the preparation methods, control means and important results in photocatalytic applications have been comprehensively reviewed, then the route to improve photocatalytic properties of BiOX has been analyzed. Finally, the application in photodetection of BiOX has been prospected.
吴 峰,张喜和. 卤氧化铋材料制备及其光电特性研究进展 Progress in Preparation and Photoelectric Properties of Bismuth Halogen Oxide[J]. 应用物理, 2019, 09(01): 51-62. https://doi.org/10.12677/APP.2019.91006
参考文献ReferencesGeim, A.K. and Grigorieva, I.V. (2013) Van der Waals Heterostructures. Nature, 499, 419-425.
<br>https://doi.org/10.1038/nature12385Chhowalla, M., Shin, H.S., Eda, G., Li, L.J., Loh, K.P. and Zhang, H. (2013) The Chemistry of Two-Dimensional Layered Transition Metal Dichalcogenide Nanosheets. Nature Chemistry, 5, 263-275.
<br>https://doi.org/10.1038/nchem.1589Nicolosi, V., Chhowalla, M., Kanatzidis, M.G., Strano, M.S. and Cole-man, J.N. (2013) Liquid Exfoliation of Layered Materials. Science, 340, Article ID: 1226419. <br>https://doi.org/10.1126/science.1226419Golberg, D., Bando, Y., Huang, Y., Terao, T., Mitome, M., Tang, C.C. and Zhi, C. (2010) Boron Nitride Nanotubes and Nanosheets. ACS Nano, 4, 2979-2993. <br>https://doi.org/10.1021/nn1006495Guo, L., Xiao, Y.C., Xu, Z.K., Lin, S.-Y. Wang, H., Chu, X.F., Gao, X.H., Zhou, L., Chi, Y.D. and Yang, X.T. (2018) Band Alignment of BiOCl/ZnO Core Shell Nanosheets by X-Ray Photoelectron Spectroscopy Measurements. Ferroelectrics, 531, 31-37.Briand, G.G. and Burford, N. (1999) Bismuth Compounds and Preparations with Biological or Medicinal Relevance. Chemical Reviews, 99, 2601-2658. <br>https://doi.org/10.1021/cr980425sPoznyak, S.K. and Kulak, A.I. (1990) Photoelectrochemical Properties of Bismuth Oxyhalide Films. Electrochimica Acta, 35, 1941-1947. <br>https://doi.org/10.1016/0013-4686(90)87103-9Xu, M.S., Liang, T., Shi, M.M. and Chen, H.Z. (2013) Graphene-Like Two-Dimensional Materials. Chemical Reviews, 113, 3766-3798. <br>https://doi.org/10.1021/cr300263aWang, X.C., Maeda, K., Thomas, A., Takanabe, K., Xin, G., Carlsson, J.M., Domen, K. and Antonietti, M. (2009) A Metal-Free Polymeric Photocatalyst for Hydrogen Production from Water under Visible Light. Nature Materials, 8, 76-80. <br>https://doi.org/10.1038/nmat2317Kato, H., Asakura, K. and Kudo, A. (2003) Highly Efficient Water Splitting into H2 and O2 over Lanthanum-Doped NaTaO3 Photocatalysts with High Crystallinity and Surface Nanostructure. Journal of the American Chemical Society, 125, 3082-3089. <br>https://doi.org/10.1021/ja027751gXiao, X.Y., Jiang, J. and Zhang, L.Z. (2013) Selective Oxidation of Benzyl Alcohol into Benzaldehyde over Semiconductors under Visible Light: The Case of Bi12O17Cl2 Nanobelts. Applied Catalysis B: Environmental, 142, 487-493.
<br>https://doi.org/10.1016/j.apcatb.2013.05.047Zhang, K.L., Liu, C.M., Huang, F.Q., Zheng, C. and Wang, W.D. (2006) Study of the Electronic Structure and Photocatalytic Activity of the BiOCl Photocatalyst. Applied Catalysis B: Environmental, 68, 125-129.
<br>https://doi.org/10.1016/j.apcatb.2006.08.002Wang, P., Wang, Y., Ye, L., Wu, M.Z., Xie, R.Z., Wang, X.D., Chen, X.S., Fan, Z.Y., Wang, J.L. and Hu, W.D. (2018) Ferroelectric Localized Field-Enhanced ZnO Nanosheet Ultra-violet Photodetector with High Sensitivity and Low Dark Current. Small, 14, Article ID: 1800492.Li, J., Yu, Y. and Zhang, L.Z. (2014) Bismuth Oxyhalide Nanomaterials: Layered Structures Meet Photocatalysis. Nanoscale, 6, 8473-8488. <br>https://doi.org/10.1039/C4NR02553AZhang, K., Liang, J., Wang, S., Liu, J., Ren, K.X., Zheng, X., Luo, H., Peng, Y.J., Zou, X., Bo, X., Li, J.H. and Yu, X.B. (2012) BiOCl Sub-Microcrystals Induced by Citric Acid and Their High Photocatalytic Activities. Crystal Growth & Design, 12, 793-803. <br>https://doi.org/10.1021/cg201112jYu, Z.Y., Detlef, B., Ralf, D., Song, L. and Lu, L.Q. (2012) Aerobic Ox-idation of 4-Tert-Butyltoluene over Cobalt and Manganese Supported Hexagonal Mesoporous Silicas as Heterogeneous Catalysts. Journal of Molecular Catalysis A: Chemical, 365, 194-202. <br>https://doi.org/10.1016/j.molcata.2012.09.004Geng, J., Hou, W.H., Lv, Y.N., Zhu, J.J. and Chen, H.Y. (2005) One-Dimensional BiPO4 Nanorods and Two-Dimensional BiOCl Lamellae: Fast Low-Temperature Sonochemical Synthesis, Characterization, and Growth Mechanism. Inorganic Chemistry, 44, 8503-8509. <br>https://doi.org/10.1021/ic050674gXiong, J.Y., Jiao, Z.B., Lu, G.X., Ren, W., Ye, J.H. and Bi, Y.P. (2013) Facile and Rapid Oxidation Fabrication of BiOCl Hierarchical Nanostructures with Enhanced Photocatalytic Properties. Chemistry: A European Journal, 19, 9472-9475. <br>https://doi.org/10.1002/chem.201300384Henle, J., Simon, P., Frenzel, A., Scholz, S. and Kaskel, S. (2007) Nanosized BiOX (X = Cl, Br, I) Particles Synthesized in Reverse Microemulsions. Chemistry of Materials, 19, 366-373. <br>https://doi.org/10.1021/cm061671kYe, L., Tian, L., Peng, T. and Zan, L. (2011) Synthesis of Highly Symmetrical BiOI Single-Crystal Nanosheets and Their {001} Fac-et-Dependent Photoactivity. Journal of Materials Chemistry, 21, 12479-12484.
<br>https://doi.org/10.1039/c1jm11005eZhao, L.J., Zhang, X.C., Fan, C.M., Liang, Z.H. and Han, P.D. (2012) First-Principles Study on the Structural, Electronic and Optical Properties of BiOX (X = Cl, Br, I) Crystals. Physica B: Condensed Matter, 407, 3364-3370.
<br>https://doi.org/10.1016/j.physb.2012.04.039Zhang, X.C., Zhao, L.J., Fan, C.M., Liang, Z.H. and Han, P.D. (2012) Effects of Oxygen Vacancy on the Electronic Structure and Absorption Spectra of Bismuth Oxychloride. Com-putational Materials Science, 61, 180-184.
<br>https://doi.org/10.1016/j.commatsci.2012.04.023Zhang, H.J., Liu, L. and Zhou, Z. (2012) First-Principles Studies on Facet-Dependent Photocatalytic Properties of Bismuth Oxyhalides (BiOXs). RSC Advances, 2, 9224-9229.Wang, W.C., Yang, W.J., Chen, R., Duan, X.B., Tian, Y.L., Zeng, D.W. and Shan, B. (2012) Inves-tigation of Band Offsets of Interface BiOCl:Bi2WO6: A First-Principles Study. Physical Chemistry Chemical Physics, 14, 2450-2454.
<br>https://doi.org/10.1039/c2cp23186gZhang, H.J., Liu, L. and Zhou, Z. (2012) Towards Better Photocatalysts: First-Principles Studies of the Alloying Effects on the Photocatalytic Activities of Bismuth Oxyhalides under Visible Light. Physical Chemistry Chemical Physics, 14, 1286-1292. <br>https://doi.org/10.1039/C1CP23516HYe, L., Su, Y., Jin, X., Xie, H. and Zhang, C. (2014) Recent Advances in BiOX (X = Cl, Br and I) Photocatalysts: Synthesis, Modification, Facet Effects and Mechanisms. Environmental Science: Nano, 1, 90-112.
<br>https://doi.org/10.1039/c3en00098bJiang, J., Zhao, K., Xiao, X.Y. and Zhang, L.Z.J. (2012) Synthesis and Facet-Dependent Photoreactivity of BiOCl Single-Crystalline Nanosheets. Journal of the American Chemical Society, 134, 4473-4476.
<br>https://doi.org/10.1021/ja210484tPare, B., Sarwan, B. and Jonnalagadda, S.B. (2011) Photocatalytic Miner-alization Study of Malachite Green on the Surface of Mn-Doped BiOCl Activated by Visible Light under Ambient Condition. Applied Surface Science, 258, 247-253. <br>https://doi.org/10.1016/j.apsusc.2011.08.040Zhang, X.C., Zhao, L.J., Fan, C.M., et al. (2012) First-Principles Investigation of Impurity Concentration Influence on Bonding Be-havior, Electronic Structure and Visible Light Absorption for Mn-Doped BiOCl Photocatalyst. Physica B, 407, 4416-4424. <br>https://doi.org/10.1016/j.physb.2012.08.002Liu, Y.Y., Son, W.J., Lu, J.B., et al. (2011) Compo-sition Dependence of the Photocatalytic Activities of BiOCl1−xBrx Solid Solutions under Visible Light. Chemistry: A European Journal, 17, 9342-9349.
<br>https://doi.org/10.1002/chem.201100952Wang, P.Q., Bai, Y., Liu, J.Y., et al. (2012) N,C-Codoped BiOCl Flower-Like Hierarchical Structures. Micro & Nano Letters, 7, 876-879. <br>https://doi.org/10.1049/mnl.2012.0496Li, J., Zhang, L.Z., Li, Y.J. and Yu, Y. (2014) Synthesis and Internal Electric Field Dependent Photoreactivity of Bi3O4Cl Single-Crystalline Nanosheets with High {001} Facet Exposure Percentages. Nanoscale, 6, 167-171.
<br>https://doi.org/10.1039/C3NR05246JCheng, H.F., Huang, B.B. and Dai, Y. (2014) Engineering BiOX (X = Cl, Br, I) Nanostructures for Highly Efficient Photocatalytic Applications. Nanoscale, 6, 2009-2026. <br>https://doi.org/10.1039/c3nr05529aLiu, G., Yu, J.C., Lu, G.Q. and Cheng, H.M. (2011) Crystal Facet Engi-neering of Semiconductor Photocatalysts: Motivations, Advances and Unique Properties. Chemical Communications, 47, 6763-6783.
<br>https://doi.org/10.1039/c1cc10665aBatzill, M. (2011) Fundamental Aspects of Surface Engineering of Transition Metal Oxide Photocatalysts. Energy & Environmental Science, 4, 3275-3286. <br>https://doi.org/10.1039/c1ee01577jCaruso, F. (2001) Nanoengineering of Particle Surfaces. Advanced Ma-terials, 13, 11-22.
<br>https://doi.org/10.1002/1521-4095(200101)13:1<11::AID-ADMA11>3.0.CO;2-NCampbell, C.T. and Sauer, J. (2013) Introduction: Surface Chemistry of Oxides. Chemical Reviews, 113, 3859-3862.
<br>https://doi.org/10.1021/cr4002337Chai, S.Y., Kim, Y.J., Jung, M.H., Chakraborty, A.K., Jung, D. and Lee, W.I. (2009) Heterojunctioned BiOCl/Bi2O3, a New Visible Light Photocatalyst. Journal of Catalysis, 262, 144-149.Shamaila, S., Sajjad, A., Chen, F. and Zhang, J. (2011) WO3/BiOCl, a Novel Heterojunction as Visible Light Photocatalyst. Journal of Colloid and Interface Science, 356, 465-472. <br>https://doi.org/10.1016/j.jcis.2011.01.015Yue, D., Chen, D., Wang, Z., Ding, H., Zong, R. and Zhu, Y. (2014) Enhancement of Visible Photocatalytic Performances of a Bi2MoO6-BiOCl Nanocomposite with Plate-on-Plate Heterojunction Structure. Physical Chemistry Chemical Physics, 16, 26314-26321. <br>https://doi.org/10.1039/C4CP03865GYoon, H.J., Choi, Y.I., Jang, E.S. and Sohn, Y. (2015) Graphene, Charcoal, ZnO, and ZnS/BiOX (X = Cl, Br, and I) Hybrid Microspheres for Photocatalytic Simulated Real Mixed Dye Treatments. Journal of Industrial and Engineering Chemistry, 32, 137-152. <br>https://doi.org/10.1016/j.jiec.2015.08.010Xu, Z.K., Han, L., Lou, B.H., Zhang, X.W. and Dong, S.J. (2014) BiOBrxI(Cl)1−x Based Spectral Tunable Photodetectors Fabricated by a Facile Interfacial Self-Assembly Strategy. Journal of Materials Chemistry C, 2, 2470.
<br>https://doi.org/10.1039/c3tc32400a