基于导电高分子自身特殊的结构及优异的物化性能,自发现之日起就成为材料学的研究热点。在智能标签(即无线射频系统,RFID)天线制印中,使用主要由导电聚合物组成导电油墨印刷RFID天线具有环保、高效和低成本的特点。而通过掺杂使导电聚合物具有高导电性无疑是研究的核心。球形聚电解质刷状物以其高度规整的对称或准对称结构、较高的接枝密度、较高的电荷密度等特性,有望成为一类新型高效的导电高分子掺杂剂。本文在概述了导电高分子一般的掺杂体系的基础上,重点介绍了球型聚电解质刷掺杂导电高分子的研究概况,并讨论二者间相互作用的机理。 Since the first discovery of conducting polymers in 1977, the field of conducting polymers has be-come one of the most active fields in materials science due to its special structure and excellent physical and chemical properties. The antenna of intelligence label, namely Radio Frequency Identification (RFID) printed mainly by conductive ink consisting of conductive polymers displays the merits of environmental protection, efficient and low cost. In past decades, considerable efforts have been devoted to improving the electrical conductivity of conducting polymers by the method of “doping”. With the advantages of spherical symmetry or quasi-symmetric structure, high grafting density and high charge density, spherical polyelectrolyte brushes (SPB) are expected to be novel dopant of conducting polymers. In this article, the trends, doping mechanism and development prospects of conducting polymers doped with spherical polyelectrolyte brushes are described on the basis of an overview of the general doping system of conducting polymers.
苏 娜. 球型聚电解质刷掺杂导电高分子研究进展Advances in the Study of Conducting Polymers Doped with Spherical Polyelectrolyte Brushes[J]. 纳米技术, 2019, 09(04): 113-121. https://doi.org/10.12677/NAT.2019.94014
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<br>https://doi.org/10.1186/s11671-015-0997-x