超疏水表面具有自清洁、减阻、防尘等多种特性,在生产生活及科研领域备受瞩目。本文综述了超疏水表面制备方法的研究进展及其在不同领域的应用进展。最后简要讨论了超疏水表面存在的不足,并对其发展方向进行了展望。
The superhydrophobic surface has attracted attentions in the field of industry and scientific re-search due to its features such as self-cleaning, drag reduction and dust-repellent properties. This article reviews the progress on the preparation of rough surface for superhydrophobicity and its application. Meanwhile, the disadvantages of superhydrophobic surfaces are evaluated and their development directions are discussed.
超疏水表面,微纳结构,表面粗糙结构, Superhydrophobic Surface Micro and Nano Structures Rough Surface超疏水表面粗糙结构的构造 及其应用研究进展
贺 胤,胡永茂,孙淑红,朱 艳. 超疏水表面粗糙结构的构造及其应用研究进展 Progress on the Fabrication of Rough Surface for Superhydrophobicity and Its Application[J]. 材料科学, 2018, 08(05): 429-437. https://doi.org/10.12677/MS.2018.85048
参考文献ReferencesGenzer, J. and Efimenko, K. (2000) Creating Long-Lived Superhydrophobic Polymer Surfaces through Mechanically Assembled Monolayers. Science, 290, 2130-2133. https://doi.org/10.1126/science.290.5499.2130Roach, P., Shirtcliffe. N.J. and Newton, M.I. (2008) Progess in Superhydrophobic Surface Development. Soft Matter, 4, 224-240. https://doi.org/10.1039/B712575PYang, Z., Wang, L., Sun, W., et al. (2017) Superhydrophobic Epoxy Coating Modified by Fluorographene Used for Anti-Corrosion and Self-Cleaning. Applied Surface Science, 401. https://doi.org/10.1016/j.apsusc.2017.01.009Zhang, X., Shi, F., Niu, J., et al. (2008) Superhydrophobic Surfaces: From Structural Control to Functional Application. Journal of Materials Chemistry, 18, 621-633. https://doi.org/10.1039/B711226BGene, W., Edward, B. and Tamir, S. (2008) The Rigorous Derivation of Young, Cassie-Baxter and Wenzel Equations and the Analysis of the Contact Angle Hysteresis Phenomenon. Chemical Physics Letters, 450, 355-359.
https://doi.org/10.1016/j.cplett.2007.11.033Polizos, G., Tuncer, E., Qiu, X., et al. (2011) Nonfunctionalized Polydimethyl Siloxane Superhydrophobic Surfaces Based on Hydrophobic-Hydrophilic Interactions. Langmuir, 27, 2953-2957. https://doi.org/10.1021/la1042712Jung, Y.C. and Bhushan, B. (2009) Dynamic Effects Induced Transition of Droplets on Biomimetic Superhydrophobic Surfaces. Langmuir, 25, 9208-9218. https://doi.org/10.1021/la900761uBhushan, B. (2012) Fabrication Techniques Used for Structures with Superhydrophobicity, Self-Cleaning, Low Adhesion/Low Drag with Antifouling Properties.Nakajima, A., Fuji-shima, A., Hashimoto, K., et al. (2000) ChemInform Abstract: Preparation of Transparent Superhydrophobic Boehmite and Silica Films by Sublimation of Aluminum Acetylacetonate. Cheminform, 31.
https://doi.org/10.1002/chin.200001251Nosonovsky, M. (2007) Multiscale Roughness and Stability of Su-perhydrophobic Biomimetic Interfaces. Langmuir, 23, 3157-3161. https://doi.org/10.1021/la062301dAccardo, A., Gentile, F., Mecarini, F., et al. (2010) In Situ X-Ray Scattering Studies of Protein Solution Droplets Drying on Micro- and Nanopatterned Superhydrophobic PMMA Surfaces. Langmuir, 26, 15057-15064.
https://doi.org/10.1021/la102958wShiu, J., Kuo, C., Chen, P., et al. (2004) Fabrication of Tunable Super-hydrophobic Surfaces by Nanosphere Lithography. Chemistry of Materials, 16, 561-564. https://doi.org/10.1021/cm034696hAccardo, A., Burghammer, M., Di, C.E., et al. (2011) Calcium Carbonate Mineralization: X-Ray Microdiffraction Probing of the Interface of an Evaporating Drop on a Superhydrophobic Surface. Langmuir, 27, 8216-8222.Darmanin, T., De Givenchy, E.T., Amigoni, S., et al. (2013) Superhydrophobic Surfaces by Electrochemical Processes. Advanced Materials, 25, 1378-1394. https://doi.org/10.1002/adma.201204300Bae, G.Y., Jang, J., Jeong, Y.G., et al. (2010) Superhydrophobic PLA Fabrics Prepared by UV Photo-Grafting of Hydrophobic Silica Particles Possessing Vinyl Groups. Journal of Colloid and Interface Science, 344, 584-587.
https://doi.org/10.1016/j.jcis.2010.01.024Balamurali, B., Breedveld, V. and Hess, D.W. (2008) Fabrication of Roll-Off and Sticky? Superhydrophobic Cellulose Surfaces via Plasma Processing. Langmuir, 24, 4785-4790. https://doi.org/10.1021/la703766cQian, B. and Shen, Z. (2005) Fabrication of Superhydrophobic Surfaces by Dislocation-Selective Chemical Etching on Aluminum, Copper, and Zinc Substrates. Langmuir the ACS Journal of Surfaces & Colloids, 21, 9007-9009.
https://doi.org/10.1021/la051308cLomga, J., Varshney, P., Nanda, D., et al. (2017) Fabrication of Durable and Regenerable Superhydrophobic Coatings with Excellent Self-Cleaning and Anti-Fogging Properties for Aluminium Surfaces. Journal of Alloys & Compounds, 702, 161-170.Michels, A.F., Soave, P.A., Nardi, J., et al. (2016) Adjustable, (super)hydrophobicity by e-Beam Deposition of Nanostructured PTFE on Textured Silicon Surfaces. Journal of Materials Science, 51, 1316-1323.
https://doi.org/10.1007/s10853-015-9449-3Feng, J., Huang, M. and Qian, X. (2009) Fabrication of Poly-ethylene Superhydrophobic Surfaces by Stretching-Controlled Micromolding. Macromolecular Materials & Engineering, 294, 295-300.
https://doi.org/10.1002/mame.200800331Xu, L., Karunakaran, R.G., Guo, J., et al. (2012) Transparent, Superhydrophobic Surfaces from One-Step Spin Coating of Hydrophobic Nanoparticles. ACS Applied Materials & In-terfaces, 4, 1118-1125. https://doi.org/10.1021/am201750hMahadik, S.A., Parale, V., Vhatkara, R.S., et al. (2013) Superhydrophobic Silica Coating by Dip Coating Method. Applied Surface Science, 277, 67-72. https://doi.org/10.1016/j.apsusc.2013.04.001Vilar, I., Yage, J.L. and Borros, S. (2016) Superhydrophobic Copper Surfaces with Anti-Corrosion Properties Fabricated by Solventless CVD Methods. ACS Applied Materials & Interfaces, 9, 1057-1065.
https://doi.org/10.1021/acsami.6b12119Simovich, T., Wu, A.H. and Lamb, R.N. (2015) Hierarchically Rough, Mechanically Durable and Superhydrophobic Epoxy Coatings through Rapid Evaporation Spray Method. Thin Solid Films, 589, 472-478.Song, X., Zhai, J., Wang, Y., et al. (2005) Fabrication of Superhydrophobic Surfaces by Self-Assembly and Their Water-Adhesion Properties. Journal of Physical Chemistry B, 109, 4048-4052. https://doi.org/10.1021/jp045152lHan, J.T., Zheng, Y., Cho, J.H., et al. (2005) Stable Superhydrophobic Organic-Inorganic Hybrid Films by Electrostatic Self-Assembly. Journal of Physical Chemistry B, 109, 20773-20778.Zhi, C., Feng, L., Hao, L., et al. (2011) One-Step Electrodeposition Process to Fabricate Cathodic Superhydrophobic Surface. Applied Surface Science, 258, 1395-1398. https://doi.org/10.1016/j.apsusc.2011.09.086Li, J., Jing, Z., Zha, F., et al. (2014) Facile Spray-Coating Process for the Fabrication of Tunable Adhesive Superhydrophobic Surfaces with Heterogeneous Chemical Composi-tions Used for Selective Transportation of Microdroplets with Different Volumes. ACS Applied Materials & Interfaces, 6, 8868-8877. https://doi.org/10.1021/am5015937Zhi, D., Lu, Y., Sathasivam, S., et al. (2017) Large-Scale Fabrication of Translucent and Repairable Superhydrophobic Spray Coatings with Remarkable Mechanical, Chemical Durability and UV Resistance. Journal of Materials Chemistry A, 5, 10622-10631.Ma, M., Mao, Y., Gupta, M., et al. (2005) Superhydrophobic Fabrics Produced by Electrospinning and Chemical Vapor Deposition. Macromolecules, 38, 9742-9748. https://doi.org/10.1021/ma0511189Zhu, Y., He, Y., Zhang, J., et al. (2017) Preparation of Large Scale, Durable, Superhydrophobic PTFE Films using Rough Glass Templates. Surface & Interface Analysis, 49, 1422-1430.Pozzato, A., Zilio, S.D., Fois, G., et al. (2006) Superhydrophobic Surfaces Fabricated by Nanoimprint Lithography. Microelectronic Engineering, 83, 884-888.Peng, C.W., Chang, K.C., Weng, C.J., et al. (2013) Nano-Casting Technique to Prepare Polyaniline Surface with Biomimetic Superhydrophobic Structures for Anticorrosion Application. Electrochimica Acta, 95, 192-199.
https://doi.org/10.1016/j.electacta.2013.02.016Bhushan, B. and Chae, J.Y. (2007) Wetting Study of Patterned Surfaces for Superhydrophobicity. Ultramicroscopy, 107, 1033-1041. https://doi.org/10.1016/j.ultramic.2007.05.002Martines, E., Seunarine, K., Morgan, H., et al. (2005) Su-perhydrophobicity and Superhydrophilicity of Regular Nanopatterns. Nano Letters, 5, 2097-2103. https://doi.org/10.1021/nl051435tZhang, J., Li, J. and Han, Y. (2010) Superhydrophobic PTFE Surfaces by Extension. Macromolecular Rapid Communications, 25, 1105-1108. https://doi.org/10.1002/marc.200400065Satoshi, S., Tomohiro, O., Naoki, S.A., et al. (1996) Super Wa-ter-Repellent Surfaces Resulting from Fractal Structure. Journal of Physical Chemistry, 100, 19512-19517. https://doi.org/10.1021/jp9616728Klein, R.J., Biesheuvel, P.M., Yu, B.C., et al. (2013) Producing Su-per-Hydrophobic Surfaces with Nano-Silica Spheres. Zeitschrift Fur Metallkunde, 94, 377-380. https://doi.org/10.3139/146.030377Ma, M., Hill, R.M., Lowery, J.L., et al. (2005) Electrospun poly(styrene-block-dimethylsiloxane) Block Copolymer Fibers Exhibiting Superhydrophobicity. Langmuir the ACS Journal of Surfaces & Colloids, 21, 5549-5554.
https://doi.org/10.1021/la047064yHuang, L., Lau, S.P., Yang, H.Y., et al. (2005) Stable Superhydrophobic Surface via Carbon Nanotubes Coated with a ZnO Thin Film. Journal of Physical Chemistry B, 109, 7746-7748. https://doi.org/10.1021/jp046549sZhao, N., Xie, Q., Weng, L., et al. (2005) Superhydrophobic Surface from Vapor-Induced Phase Separation of Copolymer Micellar Solution. Macromolecules, 38, 8996-8999. https://doi.org/10.1021/ma051560rBormashenko, E., Bormashenko, Y., Stein, T., et al. (2007) Environ-mental Scanning Electron Microscopy Study of the Fine Structure of the Triple Line and Cassie Wenzel Wetting Tran-sition for Sessile Drops Deposited on Rough Polymer Substrates. Langmuir, 23, 4378-4382. https://doi.org/10.1021/la0634802And, H.Y. and Masatsugu, S. (2005) Single-Step Fabrication of Trans-parent Superhydrophobic Porous Polymer Films. Chemistry of Materials, 17, 5231-5234. https://doi.org/10.1021/cm051281iSun, M., Luo, C., Xu, L., et al. (2005) Artificial Lotus Leaf by Nano-casting. Langmuir the ACS Journal of Surfaces & Colloids, 21, 8978-8981. https://doi.org/10.1021/la050316qZhao, Y., Li, M., Lu, Q., et al. (2008) Superhydrophobic Polyimide Films with a Hierarchical Topography: Combined Replica Molding and Layer-by-Layer Assembly. Langmuir, 24, 12651-12657. https://doi.org/10.1021/la8024364Lee, W., Jin, M.K., Woncheol, Y.A., et al. (2004) Nanostructuring of a Polymeric Substrate with Well-Defined Nanometer-Scale Topography and Tailored Surface Wet-tability. Langmuir the ACS Journal of Surfaces & Colloids, 20, 7665-7669. https://doi.org/10.1021/la049411+Li, W. and Amirfazli, A. (2005) A Thermodynamic Approach for De-termining the Contact Angle Hysteresis for Superhydrophobic Surfaces. Journal of Colloid and Interface Science, 292, 195-201.
https://doi.org/10.1016/j.jcis.2005.05.062Truesdell, R., Mammoli, A., Vorobieff, P., et al. (2006) Drag Reduction on a Patterned Superhydrophobic Surface. Physical Review Letters, 97, Article ID: 44504. https://doi.org/10.1103/PhysRevLett.97.044504Nosonovsky, M. and Bhushan, B. (2009) Multiscale Effects and Capillary Interactions in Functional Biomimetic Surfaces for Energy Conversion and Green Engineering. Philo-sophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences, 367, 1511-1539. https://doi.org/10.1098/rsta.2009.0008Nosonovsky, M. and Bhushan, B. (2008) Superhydrophobicity for Energy Conversion and Conservation Applications. Journal of Adhesion Science & Technology, 22, 2105-2115.Nosonovsky, M. and Bhushan, B. (2009) Superhydrophobic Surfaces and Emerging Applications: Non-Adhesion, Energy, Green Engineering. Current Opinion in Colloid & Interface Science, 14, 270-280.
https://doi.org/10.1016/j.cocis.2009.05.004Moore, D.F. (1975) Principles and Applications of Tribology. Pergamon Press, Oxford.Gohar, R. and Rahnejat, H. (2002) Introduction to Tribology.Bhushan, B. (2003) Adhesion and Stiction: Mechanisms, Measurement Techniques, and Methods for Reduction. Journal of Vacuum Science & Technology B Microelectronics & Nanometer Structures, 21, 2262-2296.
https://doi.org/10.1116/1.1627336Bhushan, B. (2009) Introduction: Biomimetics: Lessons from Nature—An Overview. Philosophical Transactions, 367, 1445-1486. https://doi.org/10.1098/rsta.2009.0011Bharat, B. (2007) Adhesion of Multi-Level Hierarchical Attachment Systems in Gecko Feet. Journal of Adhesion Science & Technology, 21, 1213-1258.Chen, K., Gu, K., Qiang, S., et al. (2017) Environmental Stimuli-Responsive Self-Repairing Waterbased Superhydrophobic Coatings. RSC Advances, 7, 543-550. https://doi.org/10.1039/C6RA25135H