在基材上将不同的纳米构件,如纳米点、纳米柱、纳米管、纳米球等图案化的过程是制作实用器件的先期必备步骤。常见的构建方法有光刻方法、纳米压印和铸模成型工艺、扫描探针显微镜(SPM)写入技术及模板法。模板法最吸引人的地方在于可以将模板的结构特征转移到基板表面,从而获得与模板具有相似形貌的表面图案。与光刻法(尤其是电子束和聚焦离子束刻蚀)和SPM相比,模板法适合于制造大规模有序表面结构阵列,省时且设备成本低。本文主要介绍基于PS、SiO2等微球模板的表面图案化技术,并对近年来各类图案化器件在分析化学上的应用进行了回顾。
Patterning different nano components on the substrate, such as nano dots, nano columns, nano tubes, nano spheres and so on, is an essential step in the fabrication of practical devices. The common construction methods include lithography, nano imprinting and mold forming process, scanning probe microscope (SPM) writing technology and template-based method. The most attractive aspect of the template-based method is that the structural features of the template can be transferred to the substrate surface, so as to obtain the surface pattern with similar morphology to the template. Compared with photolithography (especially electron beam and focused ion beam etching) and SPM techniques, template method is suitable for manufacturing large-scale ordered surface structure arrays, which is time-saving and low equipment cost. This paper mainly introduces the surface patterning technology based on PS, SiO2 and other microsphere templates, and reviews the application of various patterned devices in analytical chemistry in recent years.
Surface Pattern Fabrications Based on Monolayer Colloidal Crystal Templates and Related Applications
Qun Zhao, Kaiyue Wang, Dan Tian, Xuefang Gu, Shu Tian*
School of Chemistry and Chemical Engineering, Nantong University, Nantong Jiangsu
Received: Aug. 5th, 2021; accepted: Aug. 19th, 2021; published: Sep. 3rd, 2021
ABSTRACT
Patterning different nano components on the substrate, such as nano dots, nano columns, nano tubes, nano spheres and so on, is an essential step in the fabrication of practical devices. The common construction methods include lithography, nano imprinting and mold forming process, scanning probe microscope (SPM) writing technology and template-based method. The most attractive aspect of the template-based method is that the structural features of the template can be transferred to the substrate surface, so as to obtain the surface pattern with similar morphology to the template. Compared with photolithography (especially electron beam and focused ion beam etching) and SPM techniques, template method is suitable for manufacturing large-scale ordered surface structure arrays, which is time-saving and low equipment cost. This paper mainly introduces the surface patterning technology based on PS, SiO2 and other microsphere templates, and reviews the application of various patterned devices in analytical chemistry in recent years.
密堆积的胶体粒子模板还可以用来制备有序的纳米金属薄膜。在密堆积的模板上沉积约200 nm厚的金属薄膜,金属薄膜就如同一层涂料紧紧涂布于模板表面(metal film over nanosphere, MFON)使其具有规则的周期性的阵列结构。实验证明,这种纳米结构的金属薄膜具有非常好的SERS活性,尤其是Ag FONs [5]。基于此种基底,实现了许多生物和化学检测分析,包括活体检测小鼠体内葡萄糖以及炭疽病毒的检测 [6]。更重要的是,Van Duyne和他的同事们还证明了这种Ag FON SERS基底能够作为便携式的非共聚焦拉曼检测的活性基底。
赵 群,王凯悦,田 丹,顾学芳,田 澍. 基于胶体晶体模板的表面图案化构建及其应用进展Surface Pattern Fabrications Based on Monolayer Colloidal Crystal Templates and Related Applications[J]. 分析化学进展, 2021, 11(04): 229-236. https://doi.org/10.12677/AAC.2021.114024
参考文献ReferencesJones, M.R., Osberg, K.D., Macfarlane, R.J., et al. (2011) Templated Techniques for the Synthesis and Assembly of Plasmonic Nanostructures. Chemical Reviews, 111, 3736-3827. https://doi.org/10.1021/cr1004452Yan, B., Sun, K.X., Chao, K.L., et al. (2018) Fabrication of a Novel Transparent SERS Substrate Comprised of Ag-Nanoparticle Arrays and Its Application in Rapid Detection of Ractopamine on Meat. Food Analytical Methods, 11, 2329-2335. https://doi.org/10.1007/s12161-018-1216-zVelev, O.D., Lenhoff, A.M. and Kaler, E.W. (1999) A Class of Porous Metallic Nanostructures. Nature, 401, 547-548.
https://doi.org/10.1038/44065Cummins, C., Lundy, R., Walsh, J.J., et al. (2020) Enabling Future Nanomanufacturing through Block Copolymer Self-Assembly: A Review. Nano Today, 35, Article ID: 100936. https://doi.org/10.1016/j.nantod.2020.100936Camden, J.P., Dieringer, J.A., Zhao, J., et al. (2008) Controlled Plasmonic Nanostructures for Surface-Enhanced Spectroscopy and Sensing. Accounts of Chemical Research, 41, 1653-1661. https://doi.org/10.1021/ar800041sStuart, D.A., Yuen, J.M., Shah, N., et al. (2006) In Vivo Glucose Measurement by Surface-Enhanced Raman Spectroscopy. Analytical Chemistry, 78, 7211-7215. https://doi.org/10.1021/ac061238uKempa, K., Kimball, B., Rybczynski, J., et al. (2003) Photonic Crystals Based on Periodic Arrays of Aligned Carbon Nanotubes. Nano Letters, 3, 13-18. https://doi.org/10.1021/nl0258271Vogel, N., Jung, M., Bocchio, N.L., et al. (2010) Reusable Localized Surface Plasmon Sensors Based on Ultrastable Nanostructures. Small, 6, 104-109. https://doi.org/10.1002/smll.200900497Zhu, A., Zhao, X., Cheng, M., et al. (2019) Nanohoneycomb Surface-Enhanced Raman Spectroscopy-Active Chip for the Determination of Biomarkers of Hepatocellular Carcinoma. Acs Applied Materials & Interfaces, 11, 44617-44623.
https://doi.org/10.1021/acsami.9b16288Tan, J., Liu, S., Luo, J., et al. (2020) Well-Ordered Polystyrene Colloidal Spheres for Light Addressable Potentiometric Sensor. Thin Solid Films, 716, Article ID: 138417. https://doi.org/10.1016/j.tsf.2020.138417Tian, S., Zhou, Q., Gu, Z., et al. (2013) Hydrogen Peroxide Biosensor Based on Microperoxidase-11 Immobilized in a Silica Cavity Array Electrode. Talanta, 107, 324-331. https://doi.org/10.1016/j.talanta.2013.01.050Zhao, L., Zhao, L., Tian, S., et al. (2018) Ordered SiO2 Cavity Promoted Formation of Gold Single Crystal Nanoparticles towards an Efficient Electrocatalytic Application. New Journal of Chemistry, 42, 16774-16781.
https://doi.org/10.1039/C8NJ03235AGu, X., Wang, K., Qiu, J., et al. (2021) Enhanced Electrochemical and SERS Signals by Self-Assembled Gold Microelectrode Arrays: A Dual Readout Platform for Multiplex Immumoassay of Tumor Biomarkers. Sensors and Actuators B: Chemical, 334, Article ID: 129674. https://doi.org/10.1016/j.snb.2021.129674Retsch, M., Tamm, M., Bocchio, N., et al. (2009) Parallel Preparation of Densely Packed Arrays of 150-nm Gold-Nanocrescent Resonators in Three Dimensions. Small, 5, 2105-2110. https://doi.org/10.1002/smll.200900162Gwinner, M.C., Koroknay, E., Fu, L., et al. (2009) Periodic Large-Area Metallic Split-Ring Resonator Metamaterial Fabrication Based on Shadow Nanosphere Lithography. Small, 5, 400-406. https://doi.org/10.1002/smll.200800923Chen, H., Mu, S., Fang, L., et al. (2017) Polymer-Assisted Fabrication of Gold Nanoring Arrays. Nano Research, 10, 3346-3357. https://doi.org/10.1007/s12274-017-1547-xJun, C., Cong, Z., Jie, Z., et al. (2021) Raman Enhancement of Large-Area Silver Grating Arrays Based on Self-Assembled Polystyrene Microspheres. Optical Materials Express, 11, 1234-1246.
https://doi.org/10.1364/OME.422627Pravitasari, A., Negrito, M., Light, K., et al. (2018) Using Particle Lithography to Tailor the Architecture of Au Nanoparticle Plasmonic Nanoring Arrays. The Journal of Physical Chemistry B, 122, 730-736.
https://doi.org/10.1021/acs.jpcb.7b06357Kim, N.H., Kim, S., Choi, M., et al. (2018) Combination of Periodic Hybrid Nanopillar Arrays and Gold Nanorods for Improving Detection Performance of Surface-Enhanced Raman Spectroscopy. Sensors and Actuators B—Chemical, 258, 18-24. https://doi.org/10.1016/j.snb.2017.11.065Lincoln, D.R., Charlton, J.J., Hatab, N.A., et al. (2017) Surface Modification of Silicon Pillar Arrays to Enhance Fluorescence Detection of Uranium and DNA. Acs Omega, 2, 7313-7319. https://doi.org/10.1021/acsomega.7b00912Yang, M., Kim, D.S., Yoon, J.H., et al. (2016) Nanopillar Films with Polyoxometalate-Doped Polyaniline for Electrochemical Detection of Hydrogen Peroxide. Analyst, 141, 1319-1324. https://doi.org/10.1039/C5AN02134KLee, H., Yang, J.W., Liao, J.D., et al. (2020) Dielectric Nanoparticles Coated upon Silver Hollow Nanosphere as an Integrated Design to Reinforce SERS Detection of Trace Ampicillin in Milk Solution. Coatings, 10, 390.
https://doi.org/10.3390/coatings10040390Velev, O.D., Jede, T.A., Lodo, R.F., et al. (1997) Porous Silica via Colloidal Crystallization. Nature, 389, 447-448.
https://doi.org/10.1038/38921Johnson, L. and Walsh, D.A. (2011) Deposition of Silver Nanobowl Arrays Using Polystyrene Nanospheres both as Reagents and as the Templating Material. Journal of Materials Chemistry, 21, 7555-7558.
https://doi.org/10.1039/c1jm00043hBraun, P.V. and Wiltzius, P. (1999) Microporous Materials: Electrochemically Grown Photonic Crystals. Nature, 402, 603-604. https://doi.org/10.1038/45137Yang, S. and Lei, Y. (2011) Recent Progress on Surface Pattern Fabrications Based on Monolayer Colloidal Crystal Templates and Related Applications. Nanoscale, 3, 2768. https://doi.org/10.1039/c1nr10296fHuang, F.M., Wilding, D., Speed, J.D., et al. (2011) Dressing Plasmons in Particle-in-Cavity Architectures. Nano Letters, 11, 1221-1226. https://doi.org/10.1021/nl104214cTognalli, N.G., Fainstein, A., Calvo, E.J., et al. (2012) Incident Wavelength Resolved Resonant SERS on Au Sphere Segment Void (SSV) Arrays. Journal of Physical Chemistry C, 116, 3414-3420. https://doi.org/10.1021/jp211049uWang, C.H., Yang, C., Song, Y.Y., et al. (2005) Adsorption and Direct Electron Transfer from Hemoglobin into a Three-Dimensionally Ordered Macroporous Gold Film. Advanced Functional Materials, 15, 1267-1275.
https://doi.org/10.1002/adfm.200500048Zhou, Q., Zhao, J.J., Xu, W.W., et al. (2008) Formation of Two-Dimensional Ordered Cavities of Zinc Oxide and Their Confinement Effect on Electrochemical Reactions. The Journal of Physical Chemistry C, 112, 2378-2381.
https://doi.org/10.1021/jp077149iTian, S., Zhou, Q., Li, C., et al. (2012) Exploring the Chemical Enhancement of Surface-Enhanced Raman Scattering with a Designed Silver/Silica Cavity Substrate. The Journal of Physical Chemistry C, 117, 556-563.
https://doi.org/10.1021/jp309224mFan, D., Wu, S., Tian, S., et al. (2014) Detection of Dopamine on a Poly(metanilic acid) Decorated Two-Dimensional Gold Cavity Array Electrode. RSC Advances, 4, 49560-49568. https://doi.org/10.1039/C4RA07649DGu, X., Tian, S., Zhou, Q., et al. (2013) SERS Detection of Polycyclic Aromatic Hydrocarbons on a Bowl-Shaped Silver Cavity Substrate. RSC Advances, 3, 25989. https://doi.org/10.1039/c3ra43442gTian, S., Zhou, Q., Gu, Z., et al. (2013) Fabrication of a Bowl-Shaped Silver Cavity Substrate for SERS-Based Immunoassay. Analyst, 138, 2604-2612. https://doi.org/10.1039/c3an36792dGu, X., Yan, Y., Jiang, G., et al. (2014) Using a Silver-Enhanced Microarray Sandwich Structure to Improve SERS Sensitivity for Protein Detection. Analytical and BioAnalytical Chemistry, 406, 1885-1894.
https://doi.org/10.1007/s00216-013-7587-5Gu, X., She, Z., Ma, T., et al. (2018) Electrochemical Detection of Carcinoembryonic Antigen. Biosensors & Bioelectronics, 102, 610-616. https://doi.org/10.1016/j.bios.2017.12.014Gu, X., Tian, S., Chen, Y., et al. (2021) A SERS-Based Competitive Immunoassay Using Highly Ordered Gold Cavity Arrays as the Substrate for Simultaneous Detection of β-Adrenergic Agonists. Sensors and Actuators B: Chemical, 345, Article ID: 130230. https://doi.org/10.1016/j.snb.2021.130230顾学芳, 石健, 江国庆, 等. 二维银球腔阵列的制备及其在SERS检测中的应用[J]. 光谱学与光谱分析, 2013, 33(4): 987-990.